Lab 07

Solid, liquid, gas β€” it is all the same particles

Nothing changes about the molecules when ice melts. Only their energy changes, and with it how tightly they can hold onto each other. Below is a real molecular-dynamics simulation: the particles attract each other weakly, repel hard when squeezed, and do whatever the temperature lets them.

Liquid
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β€”
β€”β€”
100%
β€”Mean speed
β€”Average energy
β€”Pressure on walls
β€”Packing density
The melting and boiling points marked on the slider are this substance’s real ones at 1 atmosphere.
Energy in, temperature out

The heating curve

Keep adding heat at a steady rate and the temperature does not rise steadily. Twice it stops completely: all the energy goes into breaking bonds rather than speeding molecules up. Those flat steps are latent heat, and they are why a pan of boiling water stays at 100 Β°C however high you turn the hob.

Live speed distribution from the simulation. The smooth line is the Maxwell–Boltzmann prediction β€” no particle was told to follow it; it falls out of random collisions.

Reference

The states, and the changes between them